Preheat the oven: Set your oven to 425°F (218°C). Line a muffin tin with paper liners or lightly grease it.
Mix dry ingredients: In a large bowl, whisk together the flour, cocoa powder, granulated sugar, brown sugar, baking powder, baking soda, and salt.
Combine wet ingredients: In a separate bowl, beat the eggs, milk, oil, and vanilla extract until smooth.
Mix the batter: Pour the wet ingredients into the dry mixture and gently stir with a spatula until just combined. Don’t overmix.
Fold in chocolate chunks: Gently stir in the chocolate chunks, making sure they’re evenly distributed through the batter.
Fill muffin cups: Divide the batter evenly among the muffin cups, filling each nearly to the top. Add extra chocolate chunks on top for a bakery-style finish.
Bake muffins: Bake at 425°F for 5 minutes, then reduce the temperature to 350°F (177°C) and bake for an additional 13–15 minutes, or until a toothpick comes out with moist crumbs.
Cool and enjoy: Let the muffins cool in the pan for 5 minutes, then transfer to a wire rack. Enjoy warm or store for later.